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While the situation of these species in carcinogenesis is less well established than for the methylated bases discussed exceeding, divers lines of documentation make one think pyridyloxobutyl DNA adducts do participate in tobacco O N O N C H3 N C H2 O H O N O N N O H O N O N C H3 N N O HN O N DNA NH2 O C H3 N N N CH3 N O HN NNK CYP-catalysed -hydroxylation methanediazohydroxide (irregular) hydroxylation on methylene corps (-CH2-) hydroxylation on methyl organization (-CH3) DNA methylation fragmentationfragmentation 4-oxo-4-(3-pyridyl)-1-butane- diazohydroxide DNA pyridyloxobutylation O6-methyl-deoxyguanosine adduct (mutagenic) N7-pyridyloxobutyl-deoxyguanosine adduct (mutagenic) NH2 DNA N H N O N N Fig. The ANS has the position to trigger two hostile responses- the "departure or depart" of the sympathetic in a dither modus operandi (SNS), or the "tend and heal" of the parasympathetic edgy system. 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